Avogadro Example



Avogadro's Law Example Say you have 5.00 L of a gas which contains 0.965 mol of molecules. What will be the new volume of the gas if the quantity is increased to 1.80 mol, assuming pressure and temperature are held constant? Select the appropriate form of the law for the calculation. The Avogadro Exam is designed for Grade 11 high school students in their first high school chemistry course. Topics include: structure of matter, bonding, reactions, solutions, and gases. The test includes a few probing and demanding questions on some of the main topics of high school chemistry. Avogadro Exam date: Thursday, May 20, 2021.

  1. Avogadro's Law Equation Example
  2. Avogadro's Law Example In Real Life
  3. Avogadro's Law Example

Question: Three balloons are filled with different amounts of an ideal gas. One balloon is filled with 3 moles of the ideal gas, filling the balloon to 30 L.

a) One balloon contains 2 moles of gas. What is the volume of the balloon?

b) One balloon encloses a volume of 45 L. How many moles of gas are in the balloon?

Answer:

Avogadro’s law says the volume (V) is directly proportional to the number of molecules of gas (n) at the same temperature.

n ∝ V

Avogadro

This means the ratio of n to V is equal to a constant value.

Since this constant never changes, the ratio will always be true for different amounts of gas and volumes.

where
ni = initial number of molecules
Vi = initial volume
nf = final number of molecules
Vf = final volume.

Part a) One balloon has 3 moles of gas in 30 L. The other has 2 moles in an unknown volume. Plug these values into the above ratio:

Solve for Vf

(3 mol)Vf = (30 L)(2 mol)
(3 mol)Vf = 60 L⋅mol
Vf = 20 L

You would expect less gas to take up a smaller volume. In this case, 2 moles of gas only took up 20 L.

Part b) This time, the other balloon has a known volume of 45 L and an unknown number of moles. Start with the same ratio as before:

Use the same known values as in part a, but use 45 L for Vf.

Toshiba external hard drive driver download mac. Solve for nf

(3 mol)(45 L) = (30L)nf
135 mol⋅L = (30L)nf
nf = 4.5 moles

The larger volume means there is more gas in the balloon. In this case, there are 4.5 moles of the ideal gas in the larger balloon.

An alternative method would be to use the ratio of the known values. In part a, the known values were the number of moles. There was the second balloon had 2/3 the number of moles so it should have 2/3 of the volume and our final answer is 2/3 the known volume. The same is true of part b. The final volume is 1.5 times larger so it should have 1.5 times as many molecules. 1.5 x 3 = 4.5 which matches our answer. This is a great way to check your work.

Learning Objective

  • Define and memorize Avogadro’s number

Key Points

  • The mole allows scientists to calculate the number of elementary entities (usually atoms or molecules) in a certain mass of a given substance.
  • Avogadro’s number is an absolute number: there are 6.022×1023 elementary entities in 1 mole. This can also be written as 6.022×1023 mol-1.
  • The mass of one mole of a substance is equal to that substance’s molecular weight. For example, the mean molecular weight of water is 18.015 atomic mass units (amu), so one mole of water weight 18.015 grams.

Term

  • moleThe amount of substance of a system that contains as many elementary entities as there are atoms in 12 g of carbon-12.

The chemical changes observed in any reaction involve the rearrangement of billions of atoms. It is impractical to try to count or visualize all these atoms, but scientists need some way to refer to the entire quantity. They also need a way to compare these numbers and relate them to the weights of the substances, which they can measure and observe. The solution is the concept of the mole, which is very important in quantitative chemistry.

Avogadro’s Number

Amadeo Avogadro first proposed that the volume of a gas at a given pressure and temperature is proportional to the number of atoms or molecules, regardless of the type of gas. Although he did not determine the exact proportion, he is credited for the idea.

Avogadro’s number is a proportion that relates molar mass on an atomic scale to physical mass on a human scale. Avogadro’s number is defined as the number of elementary particles (molecules, atoms, compounds, etc.) per mole of a substance. It is equal to 6.022×1023 mol-1 and is expressed as the symbol NA.

Avogadro’s number is a similar concept to that of a dozen or a gross. A dozen molecules is 12 molecules. A gross of molecules is 144 molecules. Avogadro’s number is 6.022×1023 molecules. With Avogadro’s number, scientists can discuss and compare very large numbers, which is useful because substances in everyday quantities contain very large numbers of atoms and molecules.

The Mole

The mole (abbreviated mol) is the SI measure of quantity of a “chemical entity,” such as atoms, electrons, or protons. It is defined as the amount of a substance that contains as many particles as there are atoms in 12 grams of pure carbon-12. So, 1 mol contains 6.022×1023 elementary entities of the substance.

Chemical Computations with Avogadro’s Number and the Mole

Avogadro’s number is fundamental to understanding both the makeup of molecules and their interactions and combinations. For example, since one atom of oxygen will combine with two atoms of hydrogen to create one molecule of water (H2O), one mole of oxygen (6.022×1023 of O atoms) will combine with two moles of hydrogen (2 × 6.022×1023 of H atoms) to make one mole of H2O.

Another property of Avogadro’s number is that the mass of one mole of a substance is equal to that substance’s molecular weight. For example, the mean molecular weight of water is 18.015 atomic mass units (amu), so one mole of water weight 18.015 grams. This property simplifies many chemical computations.

If you have 1.25 grams of a molecule with molecular weight of 134.1 g/mol, how many moles of that molecule do you have?

[latex]1.25g times frac{ 1 text{ mole}}{134.1g}=0.0093 text{ moles}.[/latex]

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Avogadro's Law Equation Example

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Avogadro's Law Example

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